Reduce Greenhouse Gas Emissions Research Articles

Plasma atomic layer etching of SiO2 with a low global warming potential fluorocarbon precursor (C6F6)

Reducing greenhouse gas emissions from semiconductor manufacturing has been attracting enormous interest in both industry and academia as global warming issues have increased in significance year by year. Among various strategies, the search for etch precursors that have low global warming potential is actively underway worldwide to reduce the use of conventional precursors with high global warming potential. In this paper, we explore the use of C6F6, a promising candidate to replace the widely utilized perfluorocarbon precursor C4F8, for plasma atomic layer etching (ALE) of SiO2. In situ ellipsometry results indicated that acceptable ALE characteristics were obtained with C4F8 and C6F6 each in their own specific ALE window, while C6F6 showed superior ALE performance. Investigation into the ALE performance with different precursors was then conducted based on plasma diagnostics for radical density, electron density, and plasma potential, and the results of which showed that the difference in the radical composition between precursors significantly affected the resulting ALE trends and also that the excellent ALE performance with C6F6 might originate from its significant polymeric characteristics. We expect the present findings to contribute to the wider adoption of low global warming potential precursors in the etching process.

Reducing greenhouse gas emissions with nanofertilizers

Reducing greenhouse gas emissions with nanofertilizers

Application of enhanced combustion strategies and optimized ignition timing for achieving high thermal efficiency and low N2O emissions of marine ammonia engine at full-load condition

To meet the requirement of reducing greenhouse gas (GHG) emissions, the application of carbon-free fuel ammonia in marine engines has gained importance. However, the use of ammonia as fuel leads to low thermal efficiency and high emissions of pollutants in engines. Increasing the rate of combustion of the fuel mixture in the engine helps to solve this problem. Therefore, the influence of hydrogen volume fraction (XH2) and oxygen volume fraction (XO2) in the main chamber, via numerical simulations, on the combustion and emission characteristics of a marine ammonia engine featuring a pre-chamber. Further analysis was conducted via adjustments in the start of ignition (SOI) to optimize both engine performance and emissions. The results showed that the increase of both XH2 and XO2 contributed to the improvement of indicated thermal efficiency (ITE) and the reduction of N2O emissions. However, this is usually accompanied by higher NOx emissions, especially in the case of high XO2. In addition, adjusting the SOI resulted in the engine ITE is greater than 47.6% in each case and reduces GHG emissions by about 80% (<40 ppm N2O). Finally, chemical kinetic analysis showed that oxygen-enriched or hydrogen-enriched conditions did not change the main reaction pathway.

The Impact of Climate Change on the Development of Circular Economy in China: A Perspective on Green Total Factor Productivity

<p>In the process of China's transition to high-quality development, the circular economy, as a key strategy for achieving green growth, is of significant importance in addressing climate change and promoting sustainable development. This study employs the SBM-GML model to analyze the Green Total Factor Productivity (GTFP) of 30 provinces in China from 2005 to 2019, exploring the influence of climate change on the development of the circular economy. The research finds that although China's GTFP shows an overall upward trend, indicating some achievements in the circular economy, the performance in the eastern region significantly outperforms other regions, with technological progress being the primary driver of growth. The impact of climate change on GTFP varies with temperature changes and exhibits differentiated characteristics in different regions. Based on these findings, this paper puts forward a series of policy recommendations aimed at strengthening the practice of the circular economy, enhancing resource utilization efficiency, reducing greenhouse gas emissions, and addressing the challenges of climate change through promoting green low-carbon development, optimizing industrial structure, and formulating adaptive environmental regulations.</p>

Assessing Agricultural Impact on Greenhouse Gases in the European Union: A Climate-Smart Agriculture Perspective

With the increasing concern about climate change and its impacts on agriculture, understanding the dynamics of greenhouse gas (GHG) emissions in the European Union (EU) agricultural sector is essential for devising effective mitigation strategies. This study aims to assess the impact of agriculture on GHG within the EU and to examine how climate-smart agricultural practices can affect these emissions. The research investigates the complex relationship between agricultural activities and GHG emissions within the European Union during the period of 2017–2022 using structural equation modeling based on data from Eurostat and the European Commission. Furthermore, the study examines the influence of the digital economy on labor productivity in agriculture, recognizing the pivotal role of digital technologies in fostering climate-smart agricultural practices. The findings unveil significant positive influences encompassing the digital economy, agricultural productivity, agricultural output, and GHG emissions, underscoring the imperative of integrating climate-smart methodologies into agricultural frameworks. However, the influence of digital technologies is not significant as a result of opposing forces. Digital technologies exert positive indirect influences by increasing agricultural productivity and agricultural output, while they have negative influences by improving production processes through automation and precision agriculture. Digitalization and climate-smart agricultural practices have a significant potential to improve the efficiency and sustainability of the agricultural sector, contributing to food security and environmental protection by reducing GHG emissions. This study highlights the EU’s potential to achieve its environmental objectives through the reduction of GHG emissions and the enhancement of resilience within the agricultural sector, emphasizing the necessity of adopting climate-smart strategies.

Assessing the Role of Hydrogen in Sustainable Energy Futures: A Comprehensive Bibliometric Analysis of Research and International Collaborations in Energy and Environmental Engineering

The main results highlighted in this article underline the critical significance of hydrogen technologies in the move towards carbon neutrality. This research focuses on several key areas including the production, storage, safety, and usage of hydrogen, alongside innovative approaches for assessing hydrogen purity and production-related technologies. This study emphasizes the vital role of hydrogen storage technology for the future utilization of hydrogen as an energy carrier and the advancement of technologies that facilitate effective, safe, and cost-efficient hydrogen storage. Furthermore, bibliometric analysis has been instrumental in identifying primary research fields such as hydrogen storage, hydrogen production, efficient electrocatalysts, rotary engines utilizing hydrogen as fuel, and underground hydrogen storage. Each domain is essential for realizing a sustainable hydrogen economy, reflecting the significant research and development efforts in hydrogen technologies. Recent trends have shown an increased interest in underground hydrogen storage as a method to enhance energy security and assist in the transition towards sustainable energy systems. This research delves into the technical, economic, and environmental facets of employing geological formations for large-scale, seasonal, and long-term hydrogen storage. Ultimately, the development of hydrogen technologies is deemed crucial for meeting sustainable development goals, particularly in terms of addressing climate change and reducing greenhouse gas emissions. Hydrogen serves as an energy carrier that could substantially lessen reliance on fossil fuels while encouraging the adoption of renewable energy sources, aiding in the decarbonization of transport, industry, and energy production sectors. This, in turn, supports worldwide efforts to curb global warming and achieve carbon neutrality.

Modern mechanisms of state management of sustainable development

Aim. To analyze contemporary mechanisms of public governance of sustainable development (SD) with a focus on the energy transition and climate agenda.Objectives. To focus on strategies and practices adopted in China and Russia, comparing their approaches to achieving SD goals; to examine international experience, analyze investments in renewable energy sources (RES) and decarbonization; to review adopted regulations and management strategies in these areas; to study national and international strategies, legislation and practices aimed at increasing the share of RES and reducing carbon dioxide emissions; to assess the effectiveness of measures taken to manage SD (with special attention to the eMethods. This article is based on the analysis of data from reports of international organizations, statistical data of governmental bodies, as well as on the review of national strategies and legislation. Mechanisms and results of RES management, climate policy and decarbonization in different countries are compared.Results. Despite differences in approaches and strategic priorities, both Russia and China are making significant efforts to accelerate the transition to sustainable energy systems and reduce greenhouse gas emissions. However, China demonstrates a more active and ambitious RE policy and climate initiatives, while Russia is at an early stage of this process.Conclusions. The importance of global and regional cooperation in sharing experiences and technologies to achieve SD goals is emphasized. Both Russia and China demonstrate a growing understanding of the need to regulate SD, but their approaches and strategies differ depending on internal and external factors.

Smart Agriculture and Greenhouse Gas Emission Mitigation: A 6G-IoT Perspective

Smart farming has emerged as a promising approach to address the agriculture industry’s significant contribution to greenhouse gas (GHG) emissions. However, the effectiveness of current smart farming practices in mitigating GHG emissions remains a matter of ongoing debate. This review paper provides an in-depth examination of the current state of GHG emissions in smart farming, highlighting the limitations of existing practices in reducing GHG emissions and introducing innovative strategies that leverage the advanced capabilities of 6G-enabled IoT (6G-IoT). By enabling precise resource management, facilitating emission source identification and mitigation, and enhancing advanced emission reduction techniques, 6G-IoT integration offers a transformative solution for managing GHG emissions in agriculture. However, while smart agriculture focuses on technological applications for immediate efficiency gains, it also serves as a crucial component of sustainable agriculture by providing the tools necessary for long-term environmental supervision and resource sustainability. As a result, this study also contributes to sustainable agriculture by providing insights and guiding future advancements in smart farming, particularly in the context of 6G-IoT, to develop more effective GHG mitigation strategies for smart farming applications, promoting a more sustainable agricultural future.

Helping the climate by replacing liquefied natural gas with liquefied hydrogen or ammonia?

The war in Ukraine caused Europe to more than double its imports of liquefied natural gas (LNG) in only one year. In addition, imported LNG remains a crucial source of energy for resource-poor countries, such as Japan, where LNG imports satisfy about a quarter of the country’s primary energy demand. However, an increasing number of countries are formulating stringent decarbonization plans. Liquefied hydrogen and liquefied ammonia coupled with carbon capture and storage (LH2-CCS, LNH3-CCS) are emerging as the front runners in the search for low-carbon alternatives to LNG. Yet, little is currently known about the full environmental profile of LH2-CCS and LNH3-CCS because several characteristics of the two alternatives have only been analyzed in isolation in previous work. Here we show that the potential of these fuels to reduce greenhouse gas (GHG) emissions throughout the supply chain is highly uncertain. Our best estimate is that LH2-CCS and LNH3-CCS can reduce GHG emissions by 25%–61% relative to LNG assuming a 100 year global warming potential. However, directly coupling LNG with CCS would lead to substantial GHG reductions on the order of 74%. Further, under certain conditions, emissions from LH2-CCS and LNH3-CCS could exceed those of LNG, by up to 44%. These results question the suitability of LH2-CCS and LNH3-CCS for stringent decarbonization purposes.

Waste Utilization in Horticulture: An Overview

Waste management in horticulture plays a pivotal role in achieving environmental sustainability and optimizing resource utilization. One of the primary methods for waste utilization is composting, which involves the decomposition of organic waste materials to produce nutrient-rich compost. Compost serves as an excellent soil amendment, enhancing soil fertility and promoting plant growth. Additionally, anaerobic digestion offers a valuable approach for converting organic waste into biogas, a renewable energy source that can be used for heating, electricity generation, and vehicle fuel. Furthermore, fermentation processes can be employed to convert fruit and vegetable waste into valuable products such as animal feed and biofuels. The by-products of fermentation, including yeast and enzymes, have applications in various industries, contributing to the circular economy model. Advancements in precision agriculture and smart waste management systems have revolutionized waste utilization in horticulture. Technologies such as GPS, GIS mapping, wireless sensor networks and big data analytics enable data-driven, decision-making and optimize resource allocation. Precision planting, targeted spraying, automated pruning/harvesting and variable rate irrigation are among the innovative practices facilitated by these technologies, leading to increased productivity and efficiency in horticultural operations. Moreover, waste utilization in horticulture contributes to mitigating environmental pollution and reducing greenhouse gas emissions. By diverting organic waste from landfills and incineration, the emission of methane, a potent greenhouse gas, is minimized. Instead, organic waste is repurposed into valuable resources, thereby closing the loop on waste streams and promoting a circular economy.

Membranes with Molecular Gatekeepers for Efficient CO2 Capture and H2 Purification.

The urgent need for CO2 capture and hydrogen energy has attracted great attention owing to greenhouse gas emissions and global warming problems. Efficient CO2 capture and H2 purification with membrane technology will reduce greenhouse gas emissions and help reach a carbon-neutral society. Here, 4-sulfocalix[4]arene (SC), which has an intrinsic cavity, was embedded into the Matrimid membrane as a molecular gatekeeper for CO2 capture and H2 purification. The interactions between SC and the Matrimid polymer chains immobilize SC molecules into the interchain gaps of the Matrimid membrane, and the strong hydrogen and ionic bondings were able to form homogeneous mixed-matrix membranes. The incorporation of the SC molecular gatekeeper with exceptional molecular-sieving properties improved the gas separation performance of the mixed-matrix membranes. Compared with that of the Matrimid membrane, the CO2 permeability of the Matrimid-SC-3% membrane increased from 16.75 to 119.78 Barrer, the CO2/N2 selectivity increased from 29.39 to 106.95, and the CO2/CH4 selectivity increased from 29.91 to 140.92. Furthermore, when the permeability of H2 was increased to 172.20 Barrer, the H2/N2 and H2/CH4 selectivities reached approximately 153.75 and 202.59, respectively, which are far superior to those of most existing Matrimid-based materials. The mixed-matrix membranes also exhibited excellent long-term operation stability, with separation performance for several important gas pairs still overtaking the Robeson upper limit after aging for 400 days.

Addressing Health Equity in the Context of Carbon Capture, Utilization, and Sequestration Technologies.

To describe the role of health equity in the context of carbon capture, utilization, and sequestration (CCUS) technologies. CCUS technologies have the potential to both improve and worsen health equity. They could help reduce greenhouse gas emissions, a major contributor to climate change, but they could also have negative health impacts like air and noise pollution. More research is needed to fully understand the health equity implications of CCUS technologies. CCUS technologies have both health equity risks and benefits. Implementing misguided CCUS projects in vulnerable communities could exacerbate environmental injustice and health disparities and have the potential to increase carbon emissions. However, well-conceived projects could benefit communities through economic development. Governments, industry, and society should prioritize and expedite the reduction of CO2 emissions before considering carbon reductions via CCUS. Furthermore, CCUS projects must be thoroughly evaluated and should only proceed if they have demonstrated a net reduction in CO2 emissions and provide more benefits than risks to local communities. This underscores the importance of prioritizing health equity in the planning of CCUS projects.

Chinese organic rice transition spatial econometrics empirical analysis.

Based on the integrated model of Super-SBM model, spatial Durbin model (SDM) and Grey neural network model, this paper analyzes the panel data of various provinces in China from multiple angles and dimensions. It was found that there were significant differences in eco-efficiency between organic rice production and conventional rice production. The response of organic rice to climate change, the spatial distribution of ecological and economic benefits and the impact on carbon emission were analyzed. The results showed that organic rice planting not only had higher economic benefits, but also showed a rising trend of ecological benefits and a positive feedback effect. This finding highlights the importance of organic rice farming in reducing carbon emissions. Organic rice farming effectively reduces greenhouse gas emissions, especially carbon dioxide and methane, by improving soil management and reducing the use of fertilizers and pesticides. This has important implications for mitigating climate change and promoting soil health and biodiversity. With the acceleration of urbanization, the increase of organic rice planting area shows the trend of organic rice gradually replacing traditional rice cultivation, further highlighting the potential of organic agriculture in emission reduction, environmental protection and sustainable agricultural production. To this end, it is recommended that the Government implement a diversified support strategy to encourage technological innovation, provide guidance and training, and raise public awareness and demand for organic products. At the same time, private sector participation is stimulated to support the development of organic rice cultivation through a public-private partnership model. Through these measures, further promote organic rice cultivation, achieve the dual goals of economic benefits and environmental benefits, and effectively promote the realization of double carbon emission reduction targets.

How do we reinforce climate action?

AbstractHumanity has a shrinking window to drastically reduce greenhouse gas emissions, yet climate action is still lacking on both individual and policy levels. We argue that this is because behavioral interventions have largely neglected the basic principles of operant conditioning as one set of tools to promote collective climate action. In this perspective, we propose an operant conditioning framework that uses rewards and punishments to shape transportation, food, waste, housing, and civic actions. This framework highlights the value of reinforcement in encouraging the switch to low-emission behavior, while also considering the benefit of decreasing high-emission behavior to expedite the transition. This approach also helps explain positive and negative spillovers from behavioral interventions. This paper provides a recipe to design individual-level and system-level interventions to generate and sustain low-emission behavior to help achieve net zero emissions.

The challenges of sustainable energy transition: A focus on renewable energy

Energy is both a fundamental necessity and a driving force behind human activities. Throughout history, energy consumption has steadily risen, evolving from basic needs like food and fire for early humans to complex industrial and technological requirements today. Transitioning to a sustainable energy system requires a policy framework that empowers developing nations to promote green industries, diversify their sectors, and accelerate growth while addressing climate change and related challenges. In response to the urgent need for a global transition towards sustainable energy sources, this research explores the pivotal roles of technology, research, and policy in advancing renewable energy solutions. Motivated by the growing environmental challenges associated with conventional energy sources, the primary goal of this study is to shed light on the multifaceted strategies that facilitate the widespread adoption of renewable energy and contribute to mitigating climate change. Through an extensive analysis of renewable energy technologies, research contributions, and policy frameworks, this research uncovers critical insights. Our findings reveal how technological innovations have revolutionized renewable energy sources, making them more efficient, affordable, and scalable. Furthermore, research efforts have identified new opportunities and addressed technical challenges, while also assessing the environmental and societal impacts of renewable energy adoption. Crucially, this study underscores the indispensable role of policy in driving renewable energy transitions. Governments worldwide play a pivotal role in incentivizing renewable energy development through financial incentives, regulatory mandates, and research and development support. Moreover, these policies aim to promote energy efficiency, conservation, and equitable access to sustainable solutions. The results of this research emphasize that the transition to renewable energy is not only a viable solution to climate change but also an opportunity to create green jobs, enhance energy security, and reduce greenhouse gas emissions. The potential for a sustainable future powered by renewable energy is within reach, and this study serves as a guidepost for realizing this transformative vision.

Carbon finance and funding for forest sector climate solutions: a review and synthesis of the principles, policies, and practices

The question of funding necessary climate actions, including those in the forest sector, to drastically reduce greenhouse gas (GHG) emissions and global warming, is important to both national governments and international agencies. The objective of this paper is to address this question by reviewing and synthesizing the economic principles associated with reducing GHG emissions, the pricing mechanisms used to achieve that goal, and the diverse practices of climate finance. Included in the carbon pricing mechanisms and practices are carbon tax, compliance and voluntary emission trading, internal pricing, and funding via issuing bonds or mobilizing public budgetary resources. Then, it proceeds to describe the roles that public and private organizations can play and have played in supporting emission reduction and removal, which serves as a vital backdrop for examining current states and relative costs of forest sector initiatives. Overall, as reported by the World Bank, only about 23% of global GHG emissions are subject to any explicit price, and 75% of the emissions that are subject to a price are charged less than $10 per tCO2e. Market-based forest finance and international support for reducing emissions from deforestation and forest degradation have accounted for a small fraction of the total spent on climate mitigation and adaptation. Further, the more recent developments in carbon pricing and funding remain slow and disappointing. Without the right scale of green finance at the right time, however, it will be difficult to achieve the needed energy and economic transformation.

Adopting sea water reverse osmosis desalination technologies for sustainable development: lessons learnt from Algiers Science and Technology for membranes 2023 workshop

The city of Algiers hosted the workshop on Science and Technology for Membranes from 30th May to 1st June 2023—STM 2023, held in Algeria. The main topics focused on Reverse Osmosis (RO) desalination technologies, decentralized autonomous systems, wastewater recycling for circularity, and the effects of green membrane processes on socio-economic growth. This review examines the influence of global trends and instabilities (i.e., climate change, disrupted supply chain platforms, natural disasters) on the steady supply of freshwater. The implementation of RO desalination solutions and their sustainability are assessed based on resiliency factors, which is helpful to screen water treatment alternatives based on technological benefits, ecological safety and environmental protection. Key takeaways from this study call for rolling out local membrane production capabilities, promoting the benefits of autonomous decentralized treatment systems, prioritizing innovative solutions to reduce greenhouse gas emissions, and for developing RO-specific equipment recycling infrastructures. Implementing these new tactics can lead to mitigate water scarcity and enable a sustainable deployment of desalination membrane technologies in Algeria and its region.

The PETL and Corporate Liability for Greenhouse Gas Emissions: Duties and Remedies

Abstract How can tort law contribute to combatting climate change? The Principles of European Tort Law (PETL), in particular the framework of art 4:102 PETL, have already served as inspiration for a duty of care for both governments and companies, aimed at reducing greenhouse gas emissions. This is in line with the development of law in Europe, where liability for an insufficient contribution to combatting global warming is becoming increasingly concrete. The PETL, therefore, do not necessarily need to be amended on this point. However, the development could be strengthened in two ways. First, it is proposed to amend art 4:102(3) PETL, providing that the duty of care may be determined in part by reference to internationally recognised fundamental rights and international documents that constitute a breach of duty for companies. Secondly, making room in the PETL for injunctive relief would do justice to the need to take preventive measures, as, in climate cases, preventing global warming is more urgent than ex post compensation.

Nitrogen: from discovery, plant assimilation, sustainable usage to current enhanced efficiency fertilizers technologies – A review

ABSTRACT From 1913 onwards, the global situation changed from a scenario of nitrogen (N) scarcity to an abundance of ammonia (NH 3 ) produced synthetically via the Haber-Bosch process. Several N compounds have been synthesized since then, with urea becoming the main source of N, accounting for 55 % of current N consumption. However, N efficiency in agroecosystems is low and, normally, N recovery in cultivated plants is less than 50 %. This occurs because a large amount of reactive N is lost to the environment, inducing various forms of pollution, threatening human and environmental health, in addition to causing a negative economic impact on the farmer. The main processes responsible for low N efficiency are NH 3 volatilization, leaching, and N denitrification. Considering global NH 3 volatilization losses of 14 %, it can be assumed that up to 8.6 million Mg of urea are lost every year in the form of NH 3 . For each ton of NH 3 produced, 1.9 to 3.8 Mg of CO 2 is emitted into the atmosphere. Therefore, increasing N use efficiency (NUE) without compromising yield is a necessity and a challenge for crop improvement programs and current management systems, in addition to reducing greenhouse gas emissions. In this context, enhanced efficiency fertilizers (EEFs), which contain technologies that minimize the potential for nutrient losses compared to conventional sources, are an alternative to increasing the efficiency of nitrogen fertilization. Currently, EEFs are classified into three categories: stabilized, slow-release, and controlled-release. This study aims to understand the technologies used to produce EEFs and the factors that govern their availability to plants. This review covers the following topics: the discovery of N, N dynamics in the soil-atmosphere system, N assimilation in plants, strategies to increase NUE in agrosystems, NH 3 synthesis, NH 3 volatilization losses, N fertilizer technologies, the importance of characterization of EEFs, conventional nitrate or ammonium-based fertilizers to reduce gaseous losses of NH 3 and future prospects for the use of N fertilizers in agriculture.

Evaluating mitigation strategies for building stocks against absolute climate targets

With the growing urgency of addressing climate change it is increasingly important that decision makers at all levels are equipped to take efficient mitigation actions. This research evaluates the potential of four mitigation strategies to reduce greenhouse gas emissions from the building stock based on a case study, and these are further evaluated in terms of alignment with the remaining global emission budget and the planetary boundary for global warming. The results cover annual emissions from 2023 to 2050 across 18 impact categories, thus highlighting possible impact burden-shifting that may occur as a result of the mitigation strategies. The results show that decarbonisation of the electricity grid delivers a substantial reduction across impact categories. However, in absolute terms, this is counteracted by the increase in building stock. The results also show that current estimates for mitigation potentials are insufficient to comply with the remaining global emission budget. Thus, mitigation strategies should be even more ambitious: constructing 80% fewer new buildings and reducing operational energy demand by 80%. These findings highlight the urgency of taking multiple actions. The increase in demand for new buildings needs to be challenged. Practice relevance Present urban mitigation strategies are inadequate for meeting the stated GHG targets. To enable informed decisions it is important to quantify the effects of different strategies. Traditional life cycle assessments have static inventories and impacts can therefore not be temporarily differentiated and transparency cannot be provided on long-term potentials. This study suggests combining material flow analysis and life cycle assessment to enable integration of dynamic parameters into the life cycle inventory. This shows how the long-term effectiveness of different mitigation strategies can be evaluated. To ensure unintended burden-shifting does not occur, results cover annual emissions from 2023 to 2050 across 18 impact categories. Furthermore, this study showcases how strategies can be designed to align with global commitments such as those set by the Paris Agreement.